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Data Publication

Chemical (EPMA) and boron isotope (SIMS) analyses on tourmaline breccias from the Río Blanco-Los Bronces porphyry copper district, Chile

Hohf, Michael | Trumbull, Robert

GFZ Data Services

(2022)

Tourmaline-cemented magmatic-hydrothermal breccias are a major host to sulphide mineralization in the supergiant Río Blanco–Los Bronces (RB–LB) porphyry Cu-Mo district in central Chile. We made an extensive study of the chemical and boron isotopic composition of tourmaline from this district to shed light on the composition and origin of mineralizing fluids and to test the utility of tourmaline as an indicator mineral by comparing compositions from mineralized and barren breccias. Río Blanco-Los Bronces is a world-class porphyry-type Cu-Mo district of late Miocene age hosted in a granodioritic batholith and related porphyry intrusions in central Chile (33°9’ S latitude, 70°17’W longitude). The porphyry intrusions and related orebodies are distributed along a structurally-controlled NW-SE zone. Mineralization comprises quartz-sulfide veins, disseminated sulfide miner-alization in altered porphyry host rocks and disseminated sulfides in hydrothermal breccias. See Toro et al. (2012) for an overview of the geology, geochronology and mineralization in the district. Descriptions of the mineralized tourmaline breccias are given by Frikken et al. (2005) and Skewes et al. (2003). The data set provided here comprises in-situ chemical analyses of tourmaline by electron microprobe (EPMA) as well as in-situ boron-isotope analyses of tourmaline in the same samples by SIMS. Tourmaline was analysed in 12 samples including 8 from mineralized breccia bodies (Sur-Sur: 4, La Americana: 4), and 2 samples each from barren breccia and nearby granite-hosted tourmaline nodules in the Diamante area. We also give results of mass balance calculations testing the hypoth-esis of a magmatic-hydrothermal origin of the boron.

Keywords


Originally assigned keywords
tourmaline
porphyry copper
Andes
boron
ELECTRON MICROPROBES
SIMS

Corresponding MSL vocabulary keywords
tourmaline
boron
secondary ionization mass spectrometer

MSL enriched keywords
minerals
silicate minerals
cyclosilicates
tourmaline
measured property
boron
equipment
mass spectrometer
secondary ionization mass spectrometer
chemical elements
copper
copper
sedimentary rock
breccia
igneous rock - intrusive
acidic intrusive
granite
granodiorite
tectosilicates
quartz
Phanerozoic
Cenozoic
Neogene
Miocene
analysis
geochronology
electron probe micro-analyzer
Apparatus
microchemical analysis
electron probe micro analyser
Analyzed feature
deformation microstructure
pressure solution microstructure
vein

MSL enriched sub domains i

geochemistry
microscopy and tomography


Source publisher

GFZ Data Services


DOI

10.5880/gfz.3.1.2022.002


Authors

Hohf, Michael

0000-0002-9882-589X

TU Bergakademie Freiberg, Freiberg, Germany;

Trumbull, Robert

0000-0002-1999-4653

GFZ German Research Centre for Geosciences, Potsdam, Germany;


Contributers

Hohf, Michael

DataCollector

0000-0002-9882-589X

TU Bergakademie Freiberg, Freiberg, Germany;

Trumbull, Robert

ContactPerson

0000-0002-1999-4653

GFZ German Research Centre for Geosciences, Potsdam, Germany;

Trumbull, Robert

DataCollector

0000-0002-1999-4653

GFZ German Research Centre for Geosciences, Potsdam, Germany;

Solé, Marco

RelatedPerson

CODELCO-Chile, División Andina, Los Andes, Chile;

Microprobe Laboratory (GFZ German Research Centre for Geosciences, Germany)

HostingInstitution

GFZ German Research Centre for Geosciences. Potsdam, Germany;

Potsdam Ion Microprobe (SIMS) User Facility (GFZ German Research Centre for Geosciences, Germany)

HostingInstitution

GFZ German Research Centre for Geosciences. Potsdam, Germany;

Trumbull, Robert

ContactPerson

GFZ German Research Centre for Geosciences. Potsdam, Germany;


References

Cites

Dyar, M. D., Wiedenbeck, M., Robertson, D., Cross, L. R., Delaney, J. S., Ferguson, K., Francis, C. A., Grew, E. S., Guidotti, C. V., Hervig, R. L., Hughes, J. M., Husler, J., Leeman, W., McGuire, A. V., Rhede, D., Rothe, H., Paul, R. L., Richards, I., & Yates, M. (2001). Reference Minerals for the Microanalysis of Light Elements. Geostandards Newsletter, 25(2–3), 441–463. Portico. https://doi.org/10.1111/j.1751-908x.2001.tb00616.x

10.1111/j.1751-908X.2001.tb00616.x

Cites

Frikken, P. H., Cooke, D. R., Walshe, J. L., Archibald, D., Skarmeta, J., Serrano, L., & Vargas, R. (2005). Mineralogical and Isotopic Zonation in the Sur-Sur Tourmaline Breccia, Rio Blanco-Los Bronces Cu-Mo Deposit, Chile: Implications for Ore Genesis. Economic Geology, 100(5), 935–961. https://doi.org/10.2113/gsecongeo.100.5.935

10.2113/gsecongeo.100.5.935

Cites

Skewes, M. A., Holmgren, C., & Stern, C. R. (2002). The Donoso copper-rich, tourmaline-bearing breccia pipe in central Chile: petrologic, fluid inclusion and stable isotope evidence for an origin from magmatic fluids. Mineralium Deposita, 38(1), 2–21. https://doi.org/10.1007/s00126-002-0264-9

10.1007/s00126-002-0264-9

Cites

Cites

Yavuz, F., Karakaya, N., Yıldırım, D. K., Karakaya, M. Ç., & Kumral, M. (2014). A Windows program for calculation and classification of tourmaline-supergroup (IMA-2011). Computers & Geosciences, 63, 70–87. https://doi.org/10.1016/j.cageo.2013.10.012

10.1016/j.cageo.2013.10.012

Cites

Hohf, M., Trumbull, R. B., Cuadra, P., & Solé, M. (2023). Tourmaline Breccias from the Río Blanco-Los Bronces Porphyry Copper District, Chile: Constraints on the Fluid Source and the Utility of Tourmaline Composition for Exploration. Economic Geology, 118(4), 779–800. https://doi.org/10.5382/econgeo.4991

10.5382/econgeo.4991

IsSupplementTo


Contact

Trumbull, Robert

GFZ German Research Centre for Geosciences. Potsdam, Germany;

Trumbull, Robert

GFZ German Research Centre for Geosciences. Potsdam, Germany;


Citiation

Hohf, M., & Trumbull, R. (2022). Chemical (EPMA) and boron isotope (SIMS) analyses on tourmaline breccias from the Río Blanco-Los Bronces porphyry copper district, Chile [Data set]. GFZ Data Services. https://doi.org/10.5880/GFZ.3.1.2022.002


Geo location(s)

Study are in the Río Blanco-Los Bronces porphyry copper district, Chile