Data Publication

Mid-Ocean Ridge Basalt (MORB) Hafnium isotope data and eclogite trace element maps

Béguelin, Paul | Andersen, Morten | Elliott, Tim | Rodney, Joey

NERC EDS National Geoscience Data Centre

(2025)

Descriptions

Whole rock Hafnium (Hf) isotope data for mid-oceanic ridge basalt (MORB) samples from the Reykjanes ridge, Arctic Ocean, Equatorial Mid-Atlantic Ridge, South Mid-Atlantic Ridge, South East Indian Ridge. The Hf isotope results are not yet published but will contribute to the mantle characterisation efforts detailed in Béguelin et al. (2025) (https://doi.org/10.1029/2025GC012357). Mid-Ocean Ridge Basalt (MORB) glasses were crushed and sieved to ~600 µm. Chips were then hand-piked under a binocular microscope to remove alteration (only optically clear chips selected). Hf fractions were purified using the column chemistry protocol of Béguelin et al. (2017) and references therein (https://doi.org/10.1016/j.gca.2017.09.015). Hf isotope ratios were measured on a Nu Instruments Plasma II mass spectrometer equipped with an Aridus desolvating nebuliser, on 50 ppb solutions. Accuracy and precision were monitored with repeated measurements of the JMC-475 standard (reported in dataset). Scanning Electron Microscopy-Energy Dispersive Spectrometry (SEM EDS) and Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS) major and trace elements maps of eclogites from the Raspas complex (Ecuador). Samples were prepared as 1-inch epoxy mounts. Samples are described in John et al. (2010) (https://doi.org/10.1007/s00410-009-0427-0). The objective of this (present) work is to trace U, Pb and Th fluxes during subduction, as documented by obducted eclogites. Dataset includes SEM mapping of major elements with a Zeiss Sigma HD Field Emission Gun Analytical Scanning Electron Microscope (SEM) using energy dispersive X-ray spectroscopy (EDS). Elements measured are Fe, Ca, Cu, Ni, Mn, K, Na, Al, Mg, Ti, O, Cr, S, Si, P, Zr. Resolution is 25µm. Dataset also includes LA-ICP-MS mapping of trace elements using an Elemental Scientific ESL213 laser coupled to a Thermo Scientific iCap Q mass spectrometer. Elements measured are Rb, Sr, Mo, Cs, La, Yb, Pb, Th, U. Parameters: Raster spacing (resolution): 40µm, scan speed: 80 µm/s, rep rate: 20 Hz, fluence: 4.5 J/cm2, dwell time per element: 50 ms, injector: ESI dual concentric injector (DCI). SEM data are in weight %, LA-ICP-MS data are in µg/g (ppm). Data are unpublished, but further details can be found in the poster included with the dataset. Dataset was produced at the School of Earth and Environmental Sciences, Cardiff University, in the context of NERC grant NE/T012633/1 Mantle Circulation Constrained (MC2): A multidisciplinary 4D Earth framework for understanding mantle upwellings.

Keywords

MSL enriched keywords
metamorphic rock
eclogite
analysis
microchemical analysis
major elements
whole rock analysis
major elements
trace elements
trace elements
igneous rock - extrusive
basic extrusive
basalt
tectonic plate boundary
divergent tectonic plate boundary
plate spreading
mid-ocean ridge
measured property
hafnium
convergent tectonic plate boundary
subduction
equipment
mass spectrometer
inductively coupled plasma-mass spectrometer
laser ablation-inductively coupled plasma-mass spectrometry
x-ray spectrometer
energy-dispersive x-ray spectrometer
aluminium
calcium
chromium
cesium
copper
iron
lanthanum
lead (Pb)
magnesium
manganese
molybdenum
nickel
rubidium
sodium
strontium
thorium
titanium
ytterbium
Apparatus
electron microscopy
scanning electron microscope (SEM)
Technique
chemical and mineralogical analysis
energy dispersive x-ray spectroscopy (EDS EDX)
MSL vocabulary keywords corresponding to originally assigned keywords
eclogite
major elements
major elements
trace elements
trace elements
Originally assigned keywords
Hafnium isotopes
MORB
eclogite
major elements
trace elements
raster imaging

Metadata


MSL enriched sub domains

geochemistry
microscopy and tomography

Source


Source publisher

NERC EDS National Geoscience Data Centre

DOI


Creators

Béguelin, Paul
Personal
Cardiff University
Andersen, Morten
Personal
Cardiff University
Elliott, Tim
Personal
University of Bristol
Rodney, Joey
Personal
University of Bristol

Citation

Béguelin, P., Andersen, M., Elliott, T., & Rodney, J. (2025). Mid-Ocean Ridge Basalt (MORB) Hafnium isotope data and eclogite trace element maps [Dataset]. NERC EDS National Geoscience Data Centre. https://doi.org/10.5285/A9CBCE58-D20B-4881-A6BF-14EF7E777BCC


Dates

Available 2025-10-30

Language

- no language entry found -


Funding References

Funder Name Natural Environment Research Council
Funder Identifier https://doi.org/10.13039/501100000270
Award Number NE/T012633/1
Award Title Mantle Circulation Constrained (MC2): A multidisciplinary 4D Earth framework for understanding mantle upwellings

Locations


Geo location(s)

Reykjanes ridge, Atlantic Ocean

Arctic Ocean

Equatorial Mid-Atlantic Ridge, Atlantic Ocean

South Mid-Atlantic Ridge, Atlantic Ocean

South East Indian Ridge, Indian Ocean