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Metadata Files

Data Publication

Organochemical characterization of the mineralized Kupferschiefer in Spremberg, East Germany: Compositional and isotope data on hydrocarbons, biomarker and NSO compounds

Poetz, Stefanie | Liu, Yang | Magnall, Joseph M. | Vieth-Hillebrand, Andrea | Yang, Shengyu | Göthel, Michael | Gleeson, Sarah A. | Schulz, Hans-Martin | Karger, Cornelia | Noack, Doreen | Günther, Kristin | Kaminsky, Anke | Rothe, Heike

GFZ Data Services

(2022)

Descriptions

Organic matter (OM) is known to be an important reductant in sediment-hosted base metal deposits like the European Kupferschiefer. However, the precise nature of interactions between OM and hydrothermal fluids are still debated as well as how the interconnected reactions develop over geological timescales. This dataset provides for the first time bulk, compositional and stable isotope data of hydrocarbons, biomarkers and organonitrogen, -sulfur and-oxygen (NSO) compounds for the mineralized Kupferschiefer Spremberg-Graustein field in Eastern Germany based on samples from two drill cores. The study aims to help to better understand the role that organic matter plays during the mineralisation and formation of the sedimentary ore deposit within the Kupferschiefer with a focus on stable hydrogen isotope compositions and NSO compositional data to especially address the origin and to assess the oxidative nature of the brines that caused the mineralization in the Spremberg-Graustein field. The data publication includes bulk, compositional and stable isotope data on inorganic metals and organic matter. The data about metal contents were generated using ICP-MS while those on the organic matter were generated using Rock-Eval pyrolysis, a microscope, a Soxhlet apparatus, medium pressure liquid chromatography (MPLC), gas chromatography with flame ionization (GC-FID) and mass spectrometric detection (GC-MS), gas chromatography isotope ratio mass spectrometry (GC-IRMS) and ultrahigh resolution mass spectrometry (Fourier Transform ion cyclotron resonance mass spectrometry, FT-ICR-MS) with Electrospray ionization (ESI) and Atmospheric pressure photoionization (APPI). The full description of samples, methods and data is given in the following sections.

Keywords


Originally assigned keywords
Kupferschiefer
Permian
Organic Matter
NSO compounds
hydrogen exchange
metal porphyrins
compound specific stable hydrogen isotopic composition
FT-ICR-MS
EARTH SCIENCE > SOLID EARTH > EARTH GASES/LIQUIDS > PETROLEUM
EARTH SCIENCE > SOLID EARTH > GEOCHEMISTRY
EARTH SCIENCE > SOLID EARTH > ROCKS/MINERALS/CRYSTALS > METALS
EARTH SCIENCE > SOLID EARTH > ROCKS/MINERALS/CRYSTALS > SEDIMENTARY ROCKS

Corresponding MSL vocabulary keywords
Permian

MSL enriched keywords
Phanerozoic
Paleozoic
Permian
minerals
chemical elements
sulfur
equipment
mass spectrometer
isotope ratio mass spectrometer
gas chromatograph-mass spectrometer
inductively coupled plasma-mass spectrometer
measured property
oxygen
sulphur
ore mine

MSL enriched sub domains i

geochemistry

Source

https://dataservices.gfz-potsdam.de/panmetaworks/showshort.php?id=666f77c5-900b-11ec-b6a7-919c5bf0a567

Source publisher

GFZ Data Services


DOI

10.5880/gfz.3.2.2022.001


Creators

Poetz, Stefanie

GFZ German Research Centre for Geosiences, Potsdam, Germany

ORCID:

https://orcid.org/0000-0003-4595-7845

Liu, Yang

School of Energy resources, China University of Geosciences (Beijing), 100083 Beijing, China

ORCID:

https://orcid.org/0000-0002-2317-4316

Magnall, Joseph M.

GFZ German Research Centre for Geosiences, Potsdam, Germany

ORCID:

https://orcid.org/0000-0002-7868-3038

Vieth-Hillebrand, Andrea

GFZ German Research Centre for Geosiences, Potsdam, Germany

ORCID:

https://orcid.org/0000-0002-3688-662X

Yang, Shengyu

School of Geosciences, China University of Petroleum (East China), 266580 Qingdao, China

ORCID:

https://orcid.org/0000-0003-3730-1213

Göthel, Michael

LBGR Brandenburg State Office for Mining, Geology and Mineral Resources, Department Geology, Inselstraße 26, D-03046 Cottbus, Germany

Gleeson, Sarah A.

Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany | GFZ German Research Centre for Geosiences, Potsdam, Germany

ORCID:

https://orcid.org/0000-0002-5314-4281

Schulz, Hans-Martin

GFZ German Research Centre for Geosiences, Potsdam, Germany

ORCID:

https://orcid.org/0000-0002-9192-8626

Karger, Cornelia

GFZ German Research Centre for Geosiences, Potsdam, Germany

Noack, Doreen

GFZ German Research Centre for Geosiences, Potsdam, Germany

Günther, Kristin

GFZ German Research Centre for Geosiences, Potsdam, Germany

Kaminsky, Anke

GFZ German Research Centre for Geosiences, Potsdam, Germany

Rothe, Heike

GFZ German Research Centre for Geosiences, Potsdam, Germany


Contributors

Poetz, Stefanie

ContactPerson

GFZ German Research Centre for Geosiences, Potsdam, Germany

ORCID:

https://orcid.org/0000-0003-4595-7845

Poetz, Stefanie

DataManager

GFZ German Research Centre for Geosiences, Potsdam, Germany

ORCID:

https://orcid.org/0000-0003-4595-7845

Poetz, Stefanie

Editor

GFZ German Research Centre for Geosiences, Potsdam, Germany

ORCID:

https://orcid.org/0000-0003-4595-7845

Liu, Yang

DataCollector

School of Energy resources, China University of Geosciences (Beijing), 100083 Beijing, China

ORCID:

https://orcid.org/0000-0002-2317-4316

Liu, Yang

DataCurator

School of Energy resources, China University of Geosciences (Beijing), 100083 Beijing, China

ORCID:

https://orcid.org/0000-0002-2317-4316

Magnall, Joseph M.

DataCurator

GFZ German Research Centre for Geosiences, Potsdam, Germany

ORCID:

https://orcid.org/0000-0002-7868-3038

Vieth-Hillebrand, Andrea

DataCurator

GFZ German Research Centre for Geosiences, Potsdam, Germany

ORCID:

https://orcid.org/0000-0002-3688-662X

Yang, Shengyu

DataCollector

School of Geosciences, China University of Petroleum (East China), 266580 Qingdao, China

ORCID:

https://orcid.org/0000-0003-3730-1213

Göthel, Michael

DataCurator

LBGR Brandenburg State Office for Mining, Geology and Mineral Resources, Department Geology, Inselstraße 26, D-03046 Cottbus, Germany

Gleeson, Sarah A.

ProjectLeader

Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany | GFZ German Research Centre for Geosiences, Potsdam, Germany

ORCID:

https://orcid.org/0000-0002-5314-4281

Schulz, Hans-Martin

ProjectLeader

GFZ German Research Centre for Geosiences, Potsdam, Germany

ORCID:

https://orcid.org/0000-0002-9192-8626

Karger, Cornelia

DataCollector

GFZ German Research Centre for Geosiences, Potsdam, Germany

Noack, Doreen

DataCollector

GFZ German Research Centre for Geosiences, Potsdam, Germany

Günther, Kristin

DataCollector

GFZ German Research Centre for Geosiences, Potsdam, Germany

Kaminsky, Anke

DataCollector

GFZ German Research Centre for Geosiences, Potsdam, Germany

Rothe, Heike

DataCollector

GFZ German Research Centre for Geosiences, Potsdam, Germany

Poetz

ContactPerson

GFZ German Research Centre for Geosiences, Potsdam, Germany

Poetz

ContactPerson

GFZ German Research Centre for Geosiences, Potsdam, Germany


References

10.1021/ac50053a009

10.1016/j.gr.2009.09.004


Citation

Poetz, S., Liu, Y., Magnall, J. M., Vieth-Hillebrand, A., Yang, S., Göthel, M., Gleeson, S. A., Schulz, H.-M., Karger, C., Noack, D., Günther, K., Kaminsky, A., & Rothe, H. (2022). Organochemical characterization of the mineralized Kupferschiefer in Spremberg, East Germany: Compositional and isotope data on hydrocarbons, biomarker and NSO compounds [Data set]. GFZ Data Services. https://doi.org/10.5880/GFZ.3.2.2022.001


Dates

Issued:

2022


Funding References

Funder name: National Natural Science Foundation of China

Funder identifier: https://doi.org/10.13039/501100001809

Funder identifier type: Crossref Funder ID

Award number: 42102171

Award title: Yang Liu


Rights

Creative Commons Attribution 4.0 International


Geo location(s)

Location of drillcore 121h/72

Location of drillcore 115a/71