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Data Publication
Organochemical characterization of the mineralized Kupferschiefer in Spremberg, East Germany: Compositional and isotope data on hydrocarbons, biomarker and NSO compounds
Poetz, Stefanie | Liu, Yang | Magnall, Joseph M. | Vieth-Hillebrand, Andrea | Yang, Shengyu | Göthel, Michael | Gleeson, Sarah A. | Schulz, Hans-Martin | Karger, Cornelia | Noack, Doreen | Günther, Kristin | Kaminsky, Anke | Rothe, Heike
GFZ Data Services
(2022)
Organic matter (OM) is known to be an important reductant in sediment-hosted base metal deposits like the European Kupferschiefer. However, the precise nature of interactions between OM and hydrothermal fluids are still debated as well as how the interconnected reactions develop over geological timescales. This dataset provides for the first time bulk, compositional and stable isotope data of hydrocarbons, biomarkers and organonitrogen, -sulfur and-oxygen (NSO) compounds for the mineralized Kupferschiefer Spremberg-Graustein field in Eastern Germany based on samples from two drill cores. The study aims to help to better understand the role that organic matter plays during the mineralisation and formation of the sedimentary ore deposit within the Kupferschiefer with a focus on stable hydrogen isotope compositions and NSO compositional data to especially address the origin and to assess the oxidative nature of the brines that caused the mineralization in the Spremberg-Graustein field. The data publication includes bulk, compositional and stable isotope data on inorganic metals and organic matter. The data about metal contents were generated using ICP-MS while those on the organic matter were generated using Rock-Eval pyrolysis, a microscope, a Soxhlet apparatus, medium pressure liquid chromatography (MPLC), gas chromatography with flame ionization (GC-FID) and mass spectrometric detection (GC-MS), gas chromatography isotope ratio mass spectrometry (GC-IRMS) and ultrahigh resolution mass spectrometry (Fourier Transform ion cyclotron resonance mass spectrometry, FT-ICR-MS) with Electrospray ionization (ESI) and Atmospheric pressure photoionization (APPI). The full description of samples, methods and data is given in the following sections.
Keywords
Originally assigned keywords
Corresponding MSL vocabulary keywords
MSL enriched keywords
MSL enriched sub domains i
Source publisher
GFZ Data Services
DOI
10.5880/gfz.3.2.2022.001
Authors
Poetz, Stefanie
0000-0003-4595-7845
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Liu, Yang
0000-0002-2317-4316
School of Energy resources, China University of Geosciences (Beijing), 100083 Beijing, China;
Magnall, Joseph M.
0000-0002-7868-3038
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Vieth-Hillebrand, Andrea
0000-0002-3688-662X
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Yang, Shengyu
0000-0003-3730-1213
School of Geosciences, China University of Petroleum (East China), 266580 Qingdao, China;
Göthel, Michael
LBGR Brandenburg State Office for Mining, Geology and Mineral Resources, Department Geology, Inselstraße 26, D-03046 Cottbus, Germany;
Gleeson, Sarah A.
0000-0002-5314-4281
Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany; GFZ German Research Centre for Geosiences, Potsdam, Germany;
Schulz, Hans-Martin
0000-0002-9192-8626
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Karger, Cornelia
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Noack, Doreen
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Günther, Kristin
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Kaminsky, Anke
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Rothe, Heike
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Contributers
Poetz, Stefanie
ContactPerson
0000-0003-4595-7845
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Poetz, Stefanie
DataManager
0000-0003-4595-7845
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Poetz, Stefanie
Editor
0000-0003-4595-7845
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Liu, Yang
DataCollector
0000-0002-2317-4316
School of Energy resources, China University of Geosciences (Beijing), 100083 Beijing, China;
Liu, Yang
DataCurator
0000-0002-2317-4316
School of Energy resources, China University of Geosciences (Beijing), 100083 Beijing, China;
Magnall, Joseph M.
DataCurator
0000-0002-7868-3038
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Vieth-Hillebrand, Andrea
DataCurator
0000-0002-3688-662X
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Yang, Shengyu
DataCollector
0000-0003-3730-1213
School of Geosciences, China University of Petroleum (East China), 266580 Qingdao, China;
Göthel, Michael
DataCurator
LBGR Brandenburg State Office for Mining, Geology and Mineral Resources, Department Geology, Inselstraße 26, D-03046 Cottbus, Germany;
Gleeson, Sarah A.
ProjectLeader
0000-0002-5314-4281
Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany; GFZ German Research Centre for Geosiences, Potsdam, Germany;
Schulz, Hans-Martin
ProjectLeader
0000-0002-9192-8626
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Karger, Cornelia
DataCollector
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Noack, Doreen
DataCollector
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Günther, Kristin
DataCollector
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Kaminsky, Anke
DataCollector
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Rothe, Heike
DataCollector
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Poetz
ContactPerson
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Poetz
ContactPerson
GFZ German Research Centre for Geosiences, Potsdam, Germany;
References
to be updated
IsSupplementTo
Radke, Matthias., Willsch, Helmut., & Welte, D. H. (1980). Preparative hydrocarbon group type determination by automated medium pressure liquid chromatography. Analytical Chemistry, 52(3), 406–411. https://doi.org/10.1021/ac50053a009
10.1021/ac50053a009
Cites
Romer, R. L., & Hahne, K. (2010). Life of the Rheic Ocean: Scrolling through the shale record. Gondwana Research, 17(2–3), 236–253. https://doi.org/10.1016/j.gr.2009.09.004
10.1016/j.gr.2009.09.004
Cites
Contact
Poetz
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Poetz
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Poetz
GFZ German Research Centre for Geosiences, Potsdam, Germany;
Citiation
Poetz, S., Liu, Y., Magnall, J. M., Vieth-Hillebrand, A., Yang, S., Göthel, M., Gleeson, S. A., Schulz, H.-M., Karger, C., Noack, D., Günther, K., Kaminsky, A., & Rothe, H. (2022). Organochemical characterization of the mineralized Kupferschiefer in Spremberg, East Germany: Compositional and isotope data on hydrocarbons, biomarker and NSO compounds [Data set]. GFZ Data Services. https://doi.org/10.5880/GFZ.3.2.2022.001
Geo location(s)
Location of drillcore 121h/72
Location of drillcore 115a/71