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Data Publication
Experimental adsorption parameters of boron isotopes on clay minerals
Ring, Simon J. | Henehan, Michael J. | Blukis, Roberts | von Blanckenburg, Friedhelm
GFZ Data Services
(2024)
Adsorption and isotopic fractionation of boron on clastic sediment is one process responsible for the heavy boron isotopic composition of the modern ocean. However, the mechanism by which boron complexes to the surface of clay minerals and the cause of its isotopic fractionation are still unclear. We performed two sets of experiments, using solutions of pure water with added boron and seawater, to explore the isotope behavior during adsorption of boron onto kaolinite, smectite and illite. The dataset consists of an excel file with four sheets that store (1) the NIST RM 803 measurements we used to establish the long-term reproducibility of our isotope measurements, (2) results of our pure experiment, (3) results of our seawater experiments and (4) a global compilation of XRD-based riverine clay mineral assemblages.
Keywords
Originally assigned keywords
Corresponding MSL vocabulary keywords
MSL enriched keywords
MSL enriched sub domains i
Source publisher
GFZ Data Services
DOI
10.5880/gfz.3.3.2024.003
Authors
Ring, Simon J.
0000-0002-2645-185X
GFZ German Research Centre for Geosciences, Potsdam, Germany ; Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany;
Henehan, Michael J.
0000-0003-4706-1233
GFZ German Research Centre for Geosciences, Potsdam, Germany ; School of Earth Sciences, University of Bristol, Bristol, United Kingdom;
Blukis, Roberts
0000-0003-2999-0784
Leibniz-Institut für Kristallzüchtung (IKZ), Berlin, Germany;
von Blanckenburg, Friedhelm
0000-0002-2964-717X
GFZ German Research Centre for Geosciences, Potsdam, Germany ; Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany;
Contributers
Ring, Simon J.
ContactPerson
0000-0002-2645-185X
GFZ German Research Centre for Geosciences, Potsdam, Germany ; Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany;
Ring, Simon J.
DataCollector
0000-0002-2645-185X
GFZ German Research Centre for Geosciences, Potsdam, Germany ; Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany;
Ring, Simon J.
Researcher
0000-0002-2645-185X
GFZ German Research Centre for Geosciences, Potsdam, Germany ; Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany;
Henehan, Michael J.
DataCollector
0000-0003-4706-1233
GFZ German Research Centre for Geosciences, Potsdam, Germany ; School of Earth Sciences, University of Bristol, Bristol, United Kingdom;
Henehan, Michael J.
Researcher
0000-0003-4706-1233
GFZ German Research Centre for Geosciences, Potsdam, Germany ; School of Earth Sciences, University of Bristol, Bristol, United Kingdom;
Henehan, Michael J.
Supervisor
0000-0003-4706-1233
GFZ German Research Centre for Geosciences, Potsdam, Germany ; School of Earth Sciences, University of Bristol, Bristol, United Kingdom;
Blukis, Roberts
Researcher
0000-0003-2999-0784
Leibniz-Institut für Kristallzüchtung (IKZ), Berlin, Germany;
Blukis, Roberts
Supervisor
0000-0003-2999-0784
Leibniz-Institut für Kristallzüchtung (IKZ), Berlin, Germany;
von Blanckenburg, Friedhelm
Supervisor
0000-0002-2964-717X
GFZ German Research Centre for Geosciences, Potsdam, Germany ; Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany;
HELGES – Helmholtz-Laboratory for the Geochemistry of the Earth Surface
HostingInstitution
GFZ German Research Centre for Geosciences, Potsdam, Germany ;
Ring, Simon J.
ContactPerson
GFZ German Research Centre for Geosciences, Potsdam, Germany ;
References
to be updated
IsSupplementTo
Keren, R., & Mezuman, U. (1981). Boron Adsorption by Clay Minerals Using a Phenomenological Equation. Clays and Clay Minerals, 29(3), 198–204. https://doi.org/10.1346/ccmn.1981.0290305
10.1346/CCMN.1981.0290305
Cites
Lemarchand, D., Gaillardet, J., Lewin, É., & Allègre, C. J. (2002). Boron isotope systematics in large rivers: implications for the marine boron budget and paleo-pH reconstruction over the Cenozoic. Chemical Geology, 190(1–4), 123–140. https://doi.org/10.1016/s0009-2541(02)00114-6
10.1016/S0009-2541(02)00114-6
Cites
Lemarchand, E., Schott, J., & Gaillardet, J. (2007). How surface complexes impact boron isotope fractionation: Evidence from Fe and Mn oxides sorption experiments. Earth and Planetary Science Letters, 260(1–2), 277–296. https://doi.org/10.1016/j.epsl.2007.05.039
10.1016/j.epsl.2007.05.039
Cites
Mattigod, S. V., Frampton, J. A., & Lim, C. H. (1985). Effect of Ion-Pair Formation on Boron Adsorption by Kaolinite. Clays and Clay Minerals, 33(5), 433–437. https://doi.org/10.1346/ccmn.1985.0330509
10.1346/CCMN.1985.0330509
Cites
Palmer, M. R., Spivack, A. J., & Edmond, J. M. (1987). Temperature and pH controls over isotopic fractionation during adsorption of boron on marine clay. Geochimica et Cosmochimica Acta, 51(9), 2319–2323. https://doi.org/10.1016/0016-7037(87)90285-7
10.1016/0016-7037(87)90285-7
Cites
Contact
Ring, Simon J.
GFZ German Research Centre for Geosciences, Potsdam, Germany ;
Ring, Simon J.
GFZ German Research Centre for Geosciences, Potsdam, Germany ;
Citiation
Ring, S. J., Henehan, M. J., Blukis, R., & von Blanckenburg, F. (2024). Experimental adsorption parameters of boron isotopes on clay minerals [Data set]. GFZ Data Services. https://doi.org/10.5880/GFZ.3.3.2024.003