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Data Publication

Dissolved rhenium and other dissolved ions in Alpine catchments of the Erlenbach and Vogelbach (Switzerland) and the East River (Colorado, USA)

Hilton, Robert G | Dellinger, Mathieu

British Geological Survey - National Geoscience Data Centre (UKRI/NERC)

(2021)

The measurements and data contained here were obtained to study the chemical weathering of sedimentary rocks, and more specifically the oxidation of rock organic carbon and the associated release of CO2. The primary aim was to better understand the production and mobility of the trace element rhenium during weathering, because this element has been proposed as a proxy for rock organic carbon oxidation. The study focused on three Alpine catchments that drain sedimentary rocks, which all experience moderate to high erosion rates where oxidative weathering rates are thought to operate faster. Two catchments were located in Switzerland - the Erlenbach and Vogelbach, and one catchment in Colorado, USA - the East River. To study chemical weathering and the production and mobility of rhenium, a suite of samples were collected to capture the source and products of weathering reactions. These focused on stream and river water, river sediments and weathering profiles collected on sedimentary rocks. The Swiss catchments, water samples were collected from 2011 and 2012 to capture changes in river flow and seasonal changes in hydro-climate. Samples were collected from a gauging station operated by the Swiss Federal Institute for Forest, Snow and Landscape Research - WSL. In the East River, samples were collected from the gauging station operated by the Lawrence Berkeley National Laboratory Watershed Function Scientific Focus Area from 2015 and 2016. Additional samples included snow samples collected from the Erlenbach. All water samples were analysed for their major dissolved ion content by Ion Chromatography. Dissolved rhenium concentrations were determined by High Resolution and Quadrupole Inductively Coupled Plasma Mass Spectrometry. Solid samples were digested and analysed for Re content by ICP-MS. These geochemical measurements were paired with water discharge data to quantify the flux of dissolved elements, using rating curves and flux-weighted average methods, and interpret the hydrological context of ion production and mobility through the landscape. This new data acquisition was funded by a European Research Council Starting Grant to Robert Hilton (ROC-CO2 project, grant 678779) and a Natural Environment Research Council (NERC), UK, Standard Grant (NE/I001719/1). Further details of subsequent data analysis and interpretation can be found in Hilton, R.G., et al., 2021, Concentration-discharge relationships of dissolved rhenium in Alpine catchments reveal its use as a tracer of oxidative weathering, Water Resources Research

Keywords


Originally assigned keywords
Chemical weathering
oxidative weathering
rock organic carbon
sulphide oxidation
dissolved ions
rhenium
trace metals

Corresponding MSL vocabulary keywords
rhenium

MSL enriched keywords
measured property
rhenium
minerals
chemical elements
carbon
equipment
mass spectrometer
inductively coupled plasma-mass spectrometer
carbon (C)
organic carbon

MSL enriched sub domains i

geochemistry


Source publisher

British Geological Survey - National Geoscience Data Centre (UKRI/NERC)


DOI

10.5285/90c2e879-192e-44d7-ae2b-e9e73de80eae


Authors

Hilton, Robert G

University of Oxford; Durham University;

Dellinger, Mathieu

Durham University;


Citiation

Hilton, R. G., & Dellinger, M. (2021). Dissolved rhenium and other dissolved ions in Alpine catchments of the Erlenbach and Vogelbach (Switzerland) and the East River (Colorado, USA) [Data set]. NERC EDS National Geoscience Data Centre. https://doi.org/10.5285/90C2E879-192E-44D7-AE2B-E9E73DE80EAE


Geo location(s)

Erlenbach catchment, Switzerland

Vogelbach catchment, Switzerland

East River catchment, Colorado, USA